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Which of the following compounds is  not \textbf{ not } a constitutional isomer of a compound with an empirical formula C3H7O and a formula mass of 118.164?


A)
 Which of the following compounds is  \textbf{     not     }  a constitutional isomer of a compound with an empirical formula C<sub>3</sub>H<sub>7</sub>O and a formula mass of 118.164? A)    B)    C)    D)    E)
B)
 Which of the following compounds is  \textbf{     not     }  a constitutional isomer of a compound with an empirical formula C<sub>3</sub>H<sub>7</sub>O and a formula mass of 118.164? A)    B)    C)    D)    E)
C)
 Which of the following compounds is  \textbf{     not     }  a constitutional isomer of a compound with an empirical formula C<sub>3</sub>H<sub>7</sub>O and a formula mass of 118.164? A)    B)    C)    D)    E)
D)
 Which of the following compounds is  \textbf{     not     }  a constitutional isomer of a compound with an empirical formula C<sub>3</sub>H<sub>7</sub>O and a formula mass of 118.164? A)    B)    C)    D)    E)
E)
 Which of the following compounds is  \textbf{     not     }  a constitutional isomer of a compound with an empirical formula C<sub>3</sub>H<sub>7</sub>O and a formula mass of 118.164? A)    B)    C)    D)    E)

F) None of the above
G) All of the above

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The HNC bond angle in the cation [CH2NH2]+ is approximately ________.


A) 60°
B) 90°
C) 109.5°
D) 120°
E) 180°

F) All of the above
G) B) and C)

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Provide the condensed formulas of three structural isomers with molecular formula C5H12 and arrange them in order of increasing boiling point.

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C(CH3)4 < (C...

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The HCH bond angle in propane (CH3CH2CH3) is ________.

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approximat...

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What two hybrid atomic orbitals overlap to form the C-C s bond in allene, H2C=C=CH2?

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What is the approximate CCC bond angle in the compound below? What is the approximate CCC bond angle in the compound below?   A)  60° B)  90° C)  109.5° D)  120° E)  180°


A) 60°
B) 90°
C) 109.5°
D) 120°
E) 180°

F) A) and C)
G) B) and D)

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Anisole, the compound shown below, is an example of ________. Anisole, the compound shown below, is an example of ________.   A)  an ester B)  an ether C)  an alcohol D)  an aldehyde E)  a ketone


A) an ester
B) an ether
C) an alcohol
D) an aldehyde
E) a ketone

F) C) and E)
G) A) and D)

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Which of the following does not contain a carbonyl group?


A) aldehyde
B) ketone
C) carboxylic acid
D) ester
E) ether

F) A) and B)
G) A) and C)

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Are the two compounds shown below best described as  cis-trans isomers, constitutional isomers, \underline{\text{ cis-trans isomers, constitutional isomers, }} or  not isomeric? \underline{\text{ not isomeric? }}  Are the two compounds shown below best described as  \underline{\text{ cis-trans isomers, constitutional isomers, }}    or  \underline{\text{  not isomeric?  }}

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constituti...

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Which sequence ranks the following isomers in order of increasing boiling points? Which sequence ranks the following isomers in order of increasing boiling points?   A)  2<1<3 B)  2<3<1 C)  3<1<2 D)  3<2<1


A) 2<1<3
B) 2<3<1
C) 3<1<2
D) 3<2<1

E) None of the above
F) B) and D)

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Draw the structure of any hydrocarbon alkene which contains 4 carbon atoms.

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Which of the following best describes the relationship between the two structures shown? Which of the following best describes the relationship between the two structures shown?   A)  They represent the same compound. B)  They represent different compounds that are constitutional isomers. C)  They represent different compounds that are geometric isomers. D)  They represent different compounds that are alkenes. E)  They represent different compounds that are alkanes.


A) They represent the same compound.
B) They represent different compounds that are constitutional isomers.
C) They represent different compounds that are geometric isomers.
D) They represent different compounds that are alkenes.
E) They represent different compounds that are alkanes.

F) A) and E)
G) C) and E)

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What two hybrid atomic orbitals overlap to form the C-C s bond in acetonitrile, CH3C≡N?

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What is the hybridization of the nitrogen atom in the molecule below? What is the hybridization of the nitrogen atom in the molecule below?   A)  s B)  sp C)  sp<sup>2</sup> D)  sp<sup>3</sup> E)  none of the above


A) s
B) sp
C) sp2
D) sp3
E) none of the above

F) B) and C)
G) A) and B)

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What kind of molecular orbital (σ, σ*, π, or π*) results when the two atomic orbitals shown below interact in the manner indicated? What kind of molecular orbital (σ, σ<sup>*</sup>, π, or π<sup>*</sup>) results when the two atomic orbitals shown below interact in the manner indicated?

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How many carbon-carbon s bonds are present in the molecule shown? How many carbon-carbon s bonds are present in the molecule shown?   A)  1 B)  2 C)  3 D)  4 E)  5


A) 1
B) 2
C) 3
D) 4
E) 5

F) A) and E)
G) A) and C)

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What intermolecular forces are present among molecules in dimethyl ether, CH3OCH3?


A) London forces only
B) hydrogen bonding only
C) both London dispersion forces and hydrogen bonding
D) both London dispersion forces and dipole-dipole forces

E) None of the above
F) A) and D)

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Vildagliptin is a recently released antidiabetic drug (J. Med. Chem.  2010 \textbf{ 2010 } , 7902). Circle and name each functional group in vildagliptin.  Vildagliptin is a recently released antidiabetic drug (J. Med. Chem.  \textbf{       2010  }  , 7902). Circle and name each functional group in vildagliptin.

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Provide the hybridization of oxygen in acetaldehyde (CH3CHO) and estimate the OCH bond angle.

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The hybridization of...

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The CCC bond angle in allene (H2CCCH2) is ________.

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